A three stage model for adsorption of nonionic surfactants

Copyright @ 1993 American Institute of Physics.A three stage model for the adsorption of nonionic surfactants is proposed which makes use of existing theory from studies of random sequential adsorption. The model is simulated and the adsorption curves are found. The theory of random sequential adsorption is used to calculate the coverage exactly at the end of each of the three stages

Proposed reference models for nitrous oxide and methane in the middle atmosphere

Data from the Stratospheric and Mesospheric Sounder (SAMS) on the Nimbus 7 satellite, for the period from Jan. 1979 - Dec. 1981, are used to prepare a reference model for the long-lived trace gases, methane and nitrous oxide, in the stratosphere. The model is presented in tabular form on seventeen pressure surfaces from 20 to 0.1 mb, in 10 degree latitude bins from 50S to 70N, and for each month of the year. The means by which the data quality and interannual variability, and some of the more interesting globally and seasonally variable features of the data are discussed briefly

UNDP-GEF Grasslands Project: The Southern Africa Botanical Network SABONET

This six-year biodiversity capacity building project closes at the end of June 2005. The principal outcomes have been greatly strengthened capacities within, and interaction between, the national herbaria of southern Africa, in order to improve plant taxonomic outputs to better serve the needs of conservation end-users. Grassland plants have in many ways been the main regional focus. The project was based in the National Botanical Institute (NBI) of Southern Africa (now the South Africa Biodiversity Institute - SANBI) and had components in Angola, Botswana, Lesotho, Malawi, Mozambique, Namibia, Swaziland, Zambia and Zimbabwe. The NBI provide regional coordination and technical support

Undp-Gef Grasslands Project: The Tanzania Montane Grasslands Project

The Tanzania Southern Highlands and adjacent Nyika montane grasslands in Malawi form a distinct centre of plant diversity and endemism. The area is characterised by complex geology with old basement mountains and much more recent volcanoes (Mount Rungwe) adjacent to the rift valet faulting with Lakes Malawi (Nyasa) and Rukwa. Lake proximity generates rainfall up to 3,000 mm per annum. The maximum altitude is 3,000 m asl

Drug-like analogues of the parasitic worm-derived immunomodulator ES-62 are therapeutic in the MRL/Lpr model of systemic lupus erythematosus

Introduction ES-62, a phosphorylcholine (PC)-containing immunomodulator secreted by the parasitic worm Acanthocheilonema viteae, protects against nephritis in the MRL/Lpr mouse model of systemic lupus erythematosus (SLE). However, ES-62 is not suitable for development as a therapy and thus we have designed drug-like small molecule analogues (SMAs) based around its active PC-moiety. To provide proof of concept that ES-62-based SMAs exhibit therapeutic potential in SLE, we have investigated the capacity of two SMAs to protect against nephritis when administered to MRL/Lpr mice after onset of kidney damage. Methods SMAs 11a and 12b were evaluated for their ability to suppress antinuclear antibody (ANA) generation and consequent kidney pathology in MRL/Lpr mice when administered after the onset of proteinuria. Results SMAs 11a and 12b suppressed development of ANA and proteinuria. Protection reflected downregulation of MyD88 expression by kidney cells and this was associated with reduced production of IL-6, a cytokine that exhibits promise as a therapeutic target for this condition. Conclusions SMAs 11a and 12b provide proof of principle that synthetic compounds based on the safe immunomodulatory mechanisms of parasitic worms can exhibit therapeutic potential as a novel class of drugs for SLE, a disease for which current therapies remain inadequate

Network properties of written human language

We investigate the nature of written human language within the framework of complex network theory. In particular, we analyse the topology of Orwell's \textit{1984} focusing on the local properties of the network, such as the properties of the nearest neighbors and the clustering coefficient. We find a composite power law behavior for both the average nearest neighbor's degree and average clustering coefficient as a function of the vertex degree. This implies the existence of different functional classes of vertices. Furthermore we find that the second order vertex correlations are an essential component of the network architecture. To model our empirical results we extend a previously introduced model for language due to Dorogovtsev and Mendes. We propose an accelerated growing network model that contains three growth mechanisms: linear preferential attachment, local preferential attachment and the random growth of a pre-determined small finite subset of initial vertices. We find that with these elementary stochastic rules we are able to produce a network showing syntactic-like structures

Effect of Urinary Macromolecules and Chondroitin Sulphate on Calcium Oxalate Crystallization in Urine

After filtration and ultrafiltration (10 kD) of 24 hour urine specimens from 12 healthy male subjects, calcium oxalate crystallization was induced in the filtered (FILTD) and ultrafiltered (UF) fractions by administration of a sodium oxalate load. In addition crystallization was also induced in UF fractions to which physiological quantities of chondroitin sulphate (CHON) had been added (UF + CHON). The rate of calcium oxalate crystallization was determined by measuring the rate at which turbidity increased. Crystal numbers and sizes were measured with a Malvern particle size analyzer and by scanning electron microscopy. Crystallization rates, crystal numbers and crystal sizes were generally lower in UF fractions than in FIL TD fractions suggesting that urinary macromolecules are promoters of calcium oxalate crystallization. No increase in crystallization rate, crystal numbers or sizes occurred when chondroitin sulphate was added to UF fractions, indicating that the promoter activity of urinary macromolecules is not due to this particular glycosaminoglycan. On the contrary, crystallization rates were qualitatively lower in UF + CHON fractions than in UF fractions alone, suggesting a possible inhibitory role for chondroitin sulphate in real urine. Scanning electron microscopy revealed that while aggregates were present in UF and FILTD fractions, they were absent in UF + CHON fractions. This observation indicates that chondroitin sulphate might be an inhibitor of calcium oxalate crystal aggregation in real urine

Attraction Between Like-Charged Walls: Short-Ranged Simulations Using Local Molecular Field Theory

Effective attraction between like-charged walls mediated by counterions is studied using local molecular field (LMF) theory. Monte Carlo simulations of the "mimic system'' given by LMF theory, with short-ranged "Coulomb core" interactions in an effective single particle potential incorporating a mean-field average of the long-ranged Coulomb interactions, provide a direct test of the theory, and are in excellent agreement with more complex simulations of the full Coulomb system by Moreira and Netz [Eur. Phys. J. E 8, 33 (2002)]. A simple, generally-applicable criterion to determine the consistency parameter sigma_{min} needed for accurate use of the LMF theory is presented

The true nature of the alleged planetary nebula W16-185

We report the discovery of a small cluster of massive stars embedded in a NIR nebula in the direction of the IRAS15411-5352 point source, which is related to the alleged planetary nebula W16-185. The majority of the stars present large NIR excess characteristic of young stellar objects and have bright counterparts in the Spitzer IRAC images; the most luminous star (IRS1) is the NIR counterpart of the IRAS source. We found very strong unresolved Brgamma emission at the IRS1 position and more diluted and extended emission across the continuum nebula. From the sizes and electron volume densities we concluded that they represent ultra-compact and compact HII regions, respectively. Comparing the Brgamma emission with the 7 mm free-free emission, we estimated that the visual extinction ranges between 14 and 20 mag. We found that only one star (IRS1) can provide the number of UV photons necessary to ionize the nebula.Comment: 30 pages, 15 figures, 2 tables V3: minor grammatical changes. Figure 4 is available in pdf file. Accepted for publication in AJ, April / 200

Improved u′g′r′i′z′u'g'r'i'z' to UBVRCICUBVR_CI_C Transformation Equations for Main Sequence Stars

We report improved transformation equations between the $u'g'r'i'z'$ and $UBVR_CI_C$ photometric systems. Although the details of the transformations depend on luminosity class, we find a typical rms scatter on the order of 0.001 magnitude if the sample is limited to main sequence stars. Furthermore, we find an accurate transformation requires complex, multi-color dependencies for the bluer bandpasses. Results for giant stars will be reported in a subsequent paper.Comment: 7 pages, 8 figure